文獻名：Highly selective and sensitive probes for the detection of Cr(VI) in aqueous solutions using diglycolic acid-functionalized Au nanoparticles 

 

作者：Yang Zhang^ab, Ruixi Bai^ab, Zhigang Zhao^ab, Qiuxia Liao^ab, Peng Chen^ab, Wanghuan Guo^ab, Chunqing Cai^ab and Fan Yang ^ab 

^aCAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Xiamen 361021, China.

^bXiamen Institute of Rare Earth Materials, Haixi Institute, Chinese Academy of Sciences, Xiamen 361021, China

 

摘要：In this study, a variety of diglycolic acid-functionalized gold nanoparticle (Au NP) probes are reported, which are highly sensitive for the detection of chromium ions, Cr(VI) ions, at low concentrations in aqueous solutions based on the application of surface plasmon resonance (SPR) theory. Due to its outstanding affinity for Cr(VI) ions, the capped diglycolic acid would induce the aggregation of the NP probes upon encountering them; this was evidenced by the obvious red-shifting of the SPR peak and the enlarged size of the NPs. For the same reason, the selectivity of the probe for Cr(VI) against other heavy metal ions was found to be remarkable. Under optimized conditions, the probe showed the limit of detection (LOD) of 0.32 ppb for Cr(VI) and a linear detection scale ranging from 0.32 ppb to 0.1 ppm. To the best of our knowledge, this is probably the lowest LOD reported for Cr(VI) detection among those of the methods based on SPR.